Twilight Orb

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What it does: Unlocks Unown Tower Phase #1. Also evolves 680.gif Doublade into 681.gif Aegislash (Shield).

Where to get it: Attach 6 Rare Metals to your lineup and beat the Evolution Gym with a Fire Pokémon.

How to unlock phase: Just have your starting Pokémon with the item attached and go to the Unown Tower.